A Nano-Hybrid of Molybdenum Oxide Intercalated by Dithiocarbamate as an Oxidation Catalyst

被引:9
|
作者
Afsharpour, Maryam [1 ]
Mahjoub, Alireza [1 ]
Amini, Mostafa M. [2 ]
机构
[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran 141554838, Iran
[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran
关键词
Oxidation catalyst; Hybrid materials; Molybdenum oxide; Dithiocarbamate;
D O I
10.1007/s10904-008-9223-y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel nano-layered material based on molybdenum oxide has been synthesized by hydrothermal method using dithiocarbamate. On the basis of the X-ray diffraction, scanning electron microscopy, thermal analysis and infrared spectroscopy results, a possible arrangement of organic ligands in the interlayer space of molybdenum oxide has been proposed. Moreover, the catalytic activity of the synthesized nanohybrid of molybdenum oxide was investigated in oxygen transfer reactions. This reagent can oxidize alkenes, alcohols, sulfides, and amines in the presence of hydrogen peroxide with high yield and selectivity.
引用
收藏
页码:472 / 476
页数:5
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