Boron trifluoride etherate as a catalyst in acylation of ferrocene

被引：0

作者：

Darin, VA

Neto, AF

Miller, J

Afonso, MMD

Fonsatti, HC

Borges, ADL

机构：

[1] Univ Sao Paulo, Coll Pharmaceut Sci Ribeirao Preto, Fac Ciencias Farmaceut, BR-14040903 Ribeirao Preto, SP, Brazil

[2] Univ Sao Paulo, Fac Filosofia Ciencias & Letras, Dept Quim, BR-14040903 Ribeirao Preto, SP, Brazil

[3] Univ Fed Paraiba, Lab Tecnol Farmaceut, BR-58059900 Joao Pessoa, Paraiba, Brazil

[4] Univ Fed Paraiba, Dept Quim, BR-58059900 Joao Pessoa, Paraiba, Brazil

来源：

JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG | 1999年 / 341卷 / 06期

关键词：

organometallics; acyl ferrocenes; ferrocene;

D O I：

10.1002/(SICI)1521-3897(199908)341:6<588::AID-PRAC588>3.3.CO;2-0

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Ferrocene was acylated in acetic or propionic anhydride, in presence of boron trifluoride etherate giving acetyl ferrocene (1) (in quantitative yields) or propionyl ferrocene (2) (in high yields). A more general procedure is based on the reaction between ferrocene and carboxylic anhydrides or acyl halides in presence of ascorbic acid. Acetyl, propionyl, benzoyl, anisoyl and 3-phenyl propionyl ferrocenes (1-5) were obtained in moderate to high yields.

引用

页码：588 / 591

页数：4

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