ICP-AES determination of trace elements after preconcentrated with p-dimethylaminobenzaldehyde-modified nanometer SiO2 from sample solution

A new method that utilizes p-dimethylaminobenzaldehyde-modified nanometer SiO2 (SiO2-p-DMABD) as a solid phase extractant has been developed for simultaneous preconcentration of trace Cr(III), Cu(II), Fe(III) and Pb(II) prior to the measurement by inductively coupled plasma atomic emission spectrometry (ICP-AES). The preconcentration conditions of analytes were investigated, including the pH value, the shaking time, the mass of sorbent, the sample flow rate and volume, the elution condition and the interfering ions. The adsorption capacity of nanometer SiO2-p-DMABD was found to be (mg g(-1)) Cr(III): 6.2, Cu(II): 18.6, Fe(III): 4.7 and Pb(II): 6.0 at pH 4. The adsorbed metals were quantitatively eluted with 4 mL of 1.0 mol L-1 HCl According to the definition of IUPAC, the detection limits (3 sigma) of this method for Cr(III), Cu(II), Fe(III) and Pb(II) were 0.79, 1.27, 0.40 and 1.79 ng mL(-1), respectively. The proposed method achieved satisfied results when it was applied to the determination of trace Cr(III), Cu(II), Fe(III) and Pb(II) in biological and water samples. (c) 2006 Elsevier B.V All rights reserved.