Ordered mesoporous NiCoMnO4: synthesis and application in energy storage and catalytic decomposition of N2O

被引：0
|
作者：
Ren, Yu [1 ,3 ]
Ma, Zhen [2 ]
Bruce, Peter G. [3 ]
机构：
[1] Natl Inst Clean & Low Carbon Energy, Beijing 102209, Peoples R China
[2] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
[3] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 30期
基金：
中国国家自然科学基金; 英国工程与自然科学研究理事会;
关键词：
RECHARGEABLE LITHIUM BATTERIES; SINGLE-CRYSTAL CR2O3; LI-ION BATTERIES; MOLECULAR-SIEVES; METAL-OXIDES; COPRECIPITATION METHOD; CATHODE MATERIAL; PORE STRUCTURE; SURFACE-AREA; SILICA;
D O I：
10.1039/c2jm31644g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ordered nanocrystalline mesoporous NiCoMnO4 samples were prepared using mesoporous silica (KIT-6) as a hard template, and characterized by Powder X-Ray Diffraction (PXRD), Transmission Electron Microscopy (TEM), Energy Dispersive X-ray Spectroscopy (EDX), and N-2 adsorption-desorption. The average crystal sizes and textural properties of mesoporous NiCoMnO4 could be tuned by varying the annealing temperature (200-800 degrees C) during the synthesis. The applications as an electrochemical capacitor and in catalytic decomposition of N2O were demonstrated. Mesoporous LiNi1/3Co1/3Mn1/3O2 was further prepared by reacting mesoporous NiCoMnO4 with LiOH at 400 degrees C, and its application as a cathode material for Li-ion batteries was demonstrated.
引用
收藏
页码：15121 / 15127
页数：7
相关论文
共 50 条
  • [1] Ordered mesoporous NiMn2Ox with hematite or spinel structure: synthesis and application in electrochemical energy storage and catalytic conversion of N2O
    Ren, Yu
    Ma, Zhen
    Bruce, Peter G.
    [J]. CRYSTENGCOMM, 2011, 13 (23): : 6955 - 6959
  • [2] CATALYTIC ACTIVITY OF COBALT IMPREGNATED ON ORDERED MESOPOROUS SILICA MATERIALS IN N2O DECOMPOSITION
    Kubonova, Lenka
    Fridrichova, Dagmar
    Peikertova, Pavlina
    Mamulova Kutlakova, Katerina
    Kozubova, Svetlana
    Jiratova, Kvetuse
    Obalova, Lucie
    Cool, Pegie
    [J]. NANOCON 2015: 7TH INTERNATIONAL CONFERENCE ON NANOMATERIALS - RESEARCH & APPLICATION, 2015, : 242 - 248
  • [3] Catalytic Decomposition of N2O on Ordered Crystalline Metal Oxides
    Ma, Zhen
    Ren, Yu
    Lu, Yanbin
    Bruce, Peter G.
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2013, 13 (07) : 5093 - 5103
  • [4] Catalytic activity of cobalt grafted on ordered mesoporous silica materials in N2O decomposition and CO oxidation
    Kubonova, Lenka
    Peikertova, Pavlina
    Mamulova Kutlakova, Katerina
    Jiratovac, Kvetuse E.
    Slowik, Grzegorz
    Obalova, Lucie
    Cool, Pegie
    [J]. MOLECULAR CATALYSIS, 2017, 437 : 57 - 72
  • [5] Catalytic activity of rhodium grafted on ordered mesoporous silica materials modified with aluminum in N2O decomposition
    Kubonova, Lenka
    Fridrichova, Dagmar
    Wach, Anna
    Kustrowski, Piotr
    Obalova, Lucie
    Cool, Pegie
    [J]. CATALYSIS TODAY, 2015, 257 : 51 - 58
  • [6] Catalytic Decomposition of N2O and NO
    Obalova, Lucie
    [J]. CATALYSTS, 2021, 11 (06)
  • [7] Catalytic decomposition of N2O
    Haber, J
    Machej, T
    Janas, J
    Nattich, M
    [J]. CATALYSIS TODAY, 2004, 90 (1-2) : 15 - 19
  • [8] Facile synthesis of NiCoMnO4 nanoparticles as novel electrode materials for high-performance asymmetric energy storage devices
    Pendashteh, Afshin
    Palma, Jesus
    Anderson, Marc
    Marcilla, Rebeca
    [J]. RSC ADVANCES, 2016, 6 (34) : 28970 - 28980
  • [9] Co3O4-KIT-6 composite catalysts: synthesis, characterization, and application in catalytic decomposition of N2O
    Ma, Zhen
    Ren, Yu
    Bruce, Peter G.
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2012, 14 (08)
  • [10] Co3O4-KIT-6 composite catalysts: synthesis, characterization, and application in catalytic decomposition of N2O
    Zhen Ma
    Yu Ren
    Peter G. Bruce
    [J]. Journal of Nanoparticle Research, 2012, 14
12345