Host-guest complexation: A strategy to form sexithiophene exhibiting self-assembly properties

被引：0
|
作者：
Lagrost, C [1 ]
Lacroix, JC [1 ]
Chane-Ching, KI [1 ]
Jouini, M [1 ]
Aeiyach, S [1 ]
Lacaze, PC [1 ]
机构：
[1] Univ Paris 07, ITODYS, F-75005 Paris, France
来源：
ADVANCED MATERIALS | 1999年 / 11卷 / 08期
关键词：
D O I：
10.1002/(SICI)1521-4095(199906)11:8<664::AID-ADMA664>3.0.CO;2-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Communication: A new route for the electrosynthesis of sexithiophene (6T) films with well-ordered structure is described. Applications of oligothiophenes in organic electronic devices-to which 6T is well suited owing to its attractive charge-transport properties-necessitate a well-defined structural order. The formation of an inclusion complex of terthiophene (3T) in the host hydroxypropyl-P-cyclodextrin in an aqueous medium is demonstrated and also that the subsequent electropolymerization leads essentially to 6T. It is shown that use of the P-cyclodextrin induces an ordering effect.
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页码：664 / +
页数：5
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