A new solution of Langmuir kinetic model for dissociative adsorption on solid surfaces

被引：16
|
作者：
Bashiri, Hadis [1 ]
机构：
[1] Univ Kashan, Fac Chem, Dept Phys Chem, Kashan 8731751167, Iran
来源：
CHEMICAL PHYSICS LETTERS | 2013年 / 575卷
关键词：
STATISTICAL RATE THEORY; SOLID/SOLUTION INTERFACES; RATE-EQUATIONS; DESORPTION; NITROGEN;
D O I：
10.1016/j.cplett.2013.04.072
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this Letter, a new simple rate equation is derived to describe the rate of dissociative adsorption on solid surfaces. This rate equation is obtained according to Langmuir model for dissociative adsorption. This new equation is simple and easy to analyze. To analyze the accuracy of the new equation, several sets of hypothetical kinetic points were generated. The created points proved that results of the new equation were in a perfect agreement with our theoretical derivation. Analysis of experimental data confirms the results of the present study. Theoretical and experimental data confirmed the applicability of the new equation. (C) 2013 Elsevier B. V. All rights reserved.
引用
收藏
页码：101 / 106
页数：6
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