Solid Phase Extraction Gold from Alkaline Cyanide Solution with Benzyl Dimethyl Dodecyl Ammonium Chloride

被引:0
|
作者
Xie Run-Fang [1 ,2 ]
Yang Xiang-Jun [2 ]
Han Yun-Shan [3 ]
Li Shu-Hua [1 ]
机构
[1] Kunming Med Univ, Sch Forens Med, Kunming 650500, Peoples R China
[2] Yunnan Univ, Sch Chem Sci & Technol, Kunming 650091, Peoples R China
[3] Inspect Ctr Copper Ltd Ltd Share, Kunming 650102, Peoples R China
关键词
solid phase extraction; benzyl dimethyl dodecyl ammonium chloride(BDMDAC); alkaline cyanide solution; gold; separation; SOLVENT-EXTRACTION; SPECTROPHOTOMETRIC DETERMINATION; 3RD-PHASE; COMPLEXES; MECHANISM; TBP;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The benzyl dimethyl dodecyl ammonium chloride (BDMDAC) can react with Au(CN)(2)(-) to the ionic complex and the compound can be extracted quantitatively. At the same time, It can be enriched highly by solid phase extraction column of reversed phase bonded silica gel. Therefore, we proposed a new method of extracting gold with high enrichment multiple. What enriched by the solid phase extraction column can be eluted by ethanol and the gold in the eluent can be determinated with spectrophotometry. The solid phase extraction column was not easily damaged and it can repeat using. The method is used to extract trace amounts of gold from alkaline cyanide solution and the recovery rate of gold is higher than 98% under the optimal experimental condition.
引用
收藏
页码:487 / 491
页数:5
相关论文
共 26 条
  • [1] Study on solid phase extraction and spectrophotometric determination of vanadium with 2,3-dichloro-6-(2,7-dihydroxy-1-naphthylazo)quinoxaline
    Amin, Alaa S.
    Saber, Amr L.
    Mohammed, T. Y.
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 73 (01) : 195 - 200
  • [2] Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: Unexpected transmetalation mediated by LiAlH4
    Badiei, Yosra M.
    Jiang, Yunbo
    Widger, Leland R.
    Siegler, Maxime A.
    Goldberg, David P.
    [J]. INORGANICA CHIMICA ACTA, 2012, 382 : 19 - 26
  • [3] CHAI Yao-Dong, 2005, CHIN J GOLD, V26, P42
  • [4] Synthesis and characterization of new trinuclear copper complexes
    Ghiladi, Reza A.
    Rheingold, Arnold L.
    Siegler, Maxime A.
    Karlin, Kenneth D.
    [J]. INORGANICA CHIMICA ACTA, 2012, 389 : 131 - 137
  • [5] Solid phase extraction and spectrophotometric determination of Au(III) with 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine
    Hu, QF
    Chen, XB
    Yang, XJ
    Huang, ZJ
    Chen, J
    Yang, GY
    [J]. ANALYTICAL SCIENCES, 2006, 22 (04) : 627 - 630
  • [6] HUANG K, 2001, CHINESE J NONFERROUS, V11, P518
  • [7] HUANG K, 2001, CHINESE J NONFERROUS, V11, P307
  • [8] A novel approach in dispersive liquid-liquid microextraction based on the use of an auxiliary solvent for adjustment of density UV-VIS spectrophotometric and graphite furnace atomic absorption spectrometric determination of gold based on ion pair formation
    Kocurova, Livia
    Balogh, Ioseph S.
    Skrlikova, Jana
    Posta, Jozsef
    Andruch, Vasil
    [J]. TALANTA, 2010, 82 (05) : 1958 - 1964
  • [9] Ligand-Assisted Extraction for Separation and Preconcentration of Gold Nanoparticles from Waters
    Li, Lingxiangyu
    Leopold, Kerstin
    [J]. ANALYTICAL CHEMISTRY, 2012, 84 (10) : 4340 - 4349
  • [10] LIN Hong, 2005, CHIN J PRECIOUS META, V26, P51