Molecules-receptors: Different approaches to design effective catalysts

被引:13
|
作者
Karakhanov, Edward A. [1 ]
Karapetyan, Lyusyen M. [1 ]
Kardasheva, Yulia S. [1 ]
Maksimov, Anton L. [1 ]
Runova, Elena A. [1 ]
Terenina, Maria V. [1 ]
Filippova, Tatyana Yu. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
关键词
calixarene; cucurbituril; hydroformylation; molecular imprinting; oxidation;
D O I
10.1002/masy.200851013
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The results of studying a number of reactions catalyzed by system based on macrocyclic receptors are presented. Rh complexes with modified calix[6]- and calix[4]arene were active in the hydroformylation of unsaturated compounds. Ru catalytic system based on cucurbit[6]uril was studied in hydrogen transfer hydrogenation of water insoluble aldehydes. Molecular imprinting method application for design of catalytic systems based on cyclodextrins for naphthols dimerization and oxidative coupling styrene and benzene were discussed.
引用
收藏
页码:106 / 116
页数:11
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