Photoluminescence and Raman properties of Sb-doped ZnO thin film

被引:0
|
作者
Quan, Deng [1 ]
Ma Yong [1 ]
Yang Xiao-Hong [1 ]
Ye Li-Juan [1 ]
Zhang Xue-Zhong [1 ]
Zhang Qi [1 ]
Fu Hong-Wei [1 ]
机构
[1] Chongqing Normal Univ, Chongqing City Key Lab Optoelect Funct Mat, Opt Engn Key Lab, Chongqing 400047, Peoples R China
关键词
ZnO:Sb thin films; Raman scattering spectra; photoluminescence spectra; local vibrational mode; ELECTRICAL-PROPERTIES; LUMINESCENCE; SCATTERING; VIOLET; FE; AL; FABRICATION;
D O I
10.7498/aps.61.247701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Sb-doped ZnO thin films with various impurity content values are deposited on glass substrates by radio frequency magnetron sputtering medthods. The influences of Sb doping content on the microstructural, photoluminescence and Raman properties of ZnO film are systematically investigated by X-ray diffraction (XRD), transmission spectrum, photoluminescence (PL) spectrum and Raman scattering spectrum. The results indicate that ZnO thin film doped with Sb exhibits a hexagonal wurtzite structure with preferred c-axis orientation; The vibrational mode at 532 cm(-1) induced by Sb dopant can be observed in the Raman spectrum of the Sb-doped ZnO thin film, which can be attributed to local vibrational mode (LVMSb-O) that are formed by substituting Sb for Zn substitution and bonding O in ZnO lattice. The strong violet emission peak located at 3.11 eV is observed only in Sb-doped ZnO thin film by photoluminescence. Conbining the Raman scattering spectrum with photoluminescence, it is concluded that the strong violet emission peak is relation to Sb-Zn-O complex defect in ZnO:Sb film.
引用
收藏
页数:6
相关论文
共 40 条
  • [1] FIRST-ORDER RAMAN EFFECT IN WURTZITE-TYPE CRYSTALS
    ARGUELLO, CA
    ROUSSEAU, DL
    PORTO, SPS
    [J]. PHYSICAL REVIEW, 1969, 181 (03): : 1351 - &
  • [2] Nano-star formation in Al-doped ZnO thin film deposited by dip-dry method and its characterization using atomic force microscopy, electron probe microscopy, photo luminescence and laser Raman spectroscopy
    Behera, D.
    Acharya, B. S.
    [J]. JOURNAL OF LUMINESCENCE, 2008, 128 (10) : 1577 - 1586
  • [3] Raman scattering in ZnO thin films doped with Fe, Sb, Al, Ga, and Li
    Bundesmann, C
    Ashkenov, N
    Schubert, M
    Spemann, D
    Butz, T
    Kaidashev, EM
    Lorenz, M
    Grundmann, M
    [J]. APPLIED PHYSICS LETTERS, 2003, 83 (10) : 1974 - 1976
  • [4] Temperature-dependent shifts of three emission bands for ZnO nanoneedle arrays
    Cao, BQ
    Cai, WP
    Zeng, HB
    [J]. APPLIED PHYSICS LETTERS, 2006, 88 (16)
  • [5] Violet and blue-green luminescence from Ti-doped ZnO films deposited by RF reactive magnetron sputtering
    Chen, Haixia
    Ding, Jijun
    Ma, Shuyi
    [J]. SUPERLATTICES AND MICROSTRUCTURES, 2011, 49 (02) : 176 - 182
  • [6] High-pressure Raman spectroscopy study of wurtzite ZnO
    Decremps, F
    Pellicer-Porres, J
    Saitta, AM
    Chervin, JC
    Polian, A
    [J]. PHYSICAL REVIEW B, 2002, 65 (09): : 921011 - 921014
  • [7] Single violet luminescence emitted from ZnO films obtained by oxidation of Zn film on quartz glass
    Fan, XM
    Lian, JS
    Zhao, L
    Liu, Y
    [J]. APPLIED SURFACE SCIENCE, 2005, 252 (02) : 420 - 424
  • [8] Sb-doping of ZnO: Phase segregation and its impact on p-type doping
    Friedrich, F.
    Sieber, I.
    Klimm, C.
    Klaus, M.
    Genzel, Ch.
    Nickel, N. H.
    [J]. APPLIED PHYSICS LETTERS, 2011, 98 (13)
  • [9] Raman scattering and photoluminescence of As ion-implanted ZnO single crystal
    Jeong, TS
    Han, MS
    Youn, CJ
    Park, YS
    [J]. JOURNAL OF APPLIED PHYSICS, 2004, 96 (01) : 175 - 179
  • [10] Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition
    Jin, BJ
    Im, S
    Lee, SY
    [J]. THIN SOLID FILMS, 2000, 366 (1-2) : 107 - 110