C-H•••O non-classical hydrogen bonding in the stereomechanics of organic transformations: theory and recognition

被引：170

作者：

Johnston, Ryne C. ^{[1
]}

Cheong, Paul Ha-Yeon ^{[1
]}

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97103 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 31期

关键词：

DIELS-ALDER REACTIONS; BAYLIS-HILLMAN REACTION; ANTI-ALDOL REACTIONS; AB-INITIO; ENANTIOSELECTIVE REACTIONS; ASYMMETRIC ALLYLBORATION; TRANSITION STRUCTURES; SULFUR-DIOXIDE; LEWIS-ACIDS; ORIGINS;

D O I：

10.1039/c3ob40828k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C-H center dot center dot center dot O interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C-H center dot center dot center dot O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C-H center dot center dot center dot O interactions in modern transformations.

引用

页码：5057 / 5064

页数：8

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