Dendritic effects on the ordered assembly and the interfacial one-electron oxidation of redox-active dendron-functionalized gold nanoparticles

被引:14
|
作者
Komine, Y
Ueda, I
Goto, T
Fujihara, H [1 ]
机构
[1] Kinki Univ, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan
[2] Kinki Univ, Mol Engn Inst, Higashiosaka, Osaka 5778502, Japan
关键词
D O I
10.1039/b513078f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A higher generation dendron with a long-alkyl chain thiol (DA2-SH) induced the formation of nanoparticles with a small core with quite a narrow size distribution (1.5 +/- 0.1 nm), the self-assembly of one-dimensional arrays of these gold nanoparticles (DA2-Au), and the stabilization for the formation of the radical cation of the phenothiazine of DA2-Au nanoparticles from the interfacial one-electron oxidation of the nanoparticles with NOBF4.
引用
收藏
页码:302 / 304
页数:3
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