机构:
Siberian Res Inst Geol Geophys & Mineral Resource, Novosibirsk 630104, RussiaSiberian Res Inst Geol Geophys & Mineral Resource, Novosibirsk 630104, Russia
Mosienko, BA
[1
]
机构:
[1] Siberian Res Inst Geol Geophys & Mineral Resource, Novosibirsk 630104, Russia
phase transitions of first kind;
polymorphic transformations;
Fermat's principle in optics;
Ostwald's law of intermediate stages;
heat conductivity of solids;
D O I:
10.1524/zpch.2005.219.12.1655
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Fermat's principle of least time and Ostwald's law of intermediate stages are postulates concerning the physical processes that deal with light and heat energy flows, respectively. A comparative analysis of these processes shows that there is a close analogy between them. This suggests that the principle of least time can be applied to phase transitions of first kind concerned Ostwald's law. This supposition has been proven using the Maxwell-Boltzmann distribution law and an assumed correlation between two parameters of solids (heat conductivity and activation energy of molecules). Thus, a modification of Fermat's principle is obtained, which can be named Fermat-Ostwald principle.
机构:
Univ Paris Diderot, Lab SPHERE, UMR 7219, 2 Pl Jussieu, F-75005 Paris, France
CNRS, Paris, France
Univ Tokyo, Tokyo, JapanUniv Paris Diderot, Lab SPHERE, UMR 7219, 2 Pl Jussieu, F-75005 Paris, France