Synthesis and reactivity of 1-chloro-2-methylthio-ferrocene and 1,1′-dichloro-2,2′-bis(methylthio)ferrocene. Molecular structure of 1-chloro-2,5-bis(methylthio)ferrocene

被引：4

作者：

Bernhartzeder, Stefanie ^{[1
]}

Kempinger, Werner ^{[1
]}

Suenkel, Karlheinz ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 752卷

关键词：

Chloroferrocenes; Thioferrocenes; Lithiation; X-ray structure determination; MULTIDENTATE FERROCENE LIGANDS; DIRECTED METALATION REACTIONS; DERIVATIVES; LITHIATION; ROUTE; CHLOROFERROCENE; HALOFERROCENES; COMPLEXATION;

D O I：

10.1016/j.jorganchem.2013.12.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lithiation of chloroferrocene (1a) with n-butyl lithium or lithium tetramethylpiperidinide (LiTMP) followed by addition of dimethyldisulfide gives 1-chloro-2-methylthioferrocene (2). Renewed treatment of 2 with LiTMP and MeSSMe yields 1-chloro-2,5-bis(methylthio)ferrocene (3), the structure of which was determined by X-ray diffraction. The reaction of 1,1'-dichloroferrocene (1b) with n-butyl lithium in the presence of TMEDA followed by addition of MeSSMe gives 1,1'-dichloro-2,2'-bis(methylthio)ferrocene as a diastereomeric 1: 2 mixture of the meso and D, L form. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：147 / 151

页数：5

共 50 条

[1] THE SYNTHESIS AND STEREODYNAMICS OF PLATINUM(II) CHLORIDE COMPLEXES OF 1,1'-BIS(METHYLTHIO)FERROCENE, 1,1'-BIS(METHYLSELENO)FERROCENE AND 1,1'-BIS(METHYLTHIO)RUTHENOCENE
ABEL, EW
LONG, NJ
ORRELL, KG
OSBORNE, AG
SIK, V
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 405 (03) : 375 - 382
[2] 1,1′-Dibromo-2,2′,5,5′-tetrakis(methylthio)ferrocene
Blockhaus, Tobias
Zott, Fabian
Suenkel, Karlheinz
MOLBANK, 2023, 2023 (01)
[3] Synthesis and characterization of 1,1′-bis(2-ethanol)ferrocene.
Barry, KP
Nataro, C
Herber, RH
Rheingold, AL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U735 - U735
[4] Electrochemistry of 1,1′-bis(diphenylphosphino)ferrocene.
Nataro, C
Campbell, AN
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U701 - U701
[5] STRUCTURE OF 1,1'-2,2'-BIS(OXYBISMETHYLENE)FERROCENE
GEIB, SJ
RAO, SJ
PETTER, RC
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 25 - 27
[6] STRUCTURE OF 2,2-BIS(METHYLTHIO)-1,1-ETHYLENEDICARBONITRILE
HUMMEL, HU
PROCHER, H
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 1602 - 1604
[7] Synthesis and characterization of nickel and palladium complexes with 1,1'-bis(diphenylphosphino)ferrocene.
Norris, CM
Schreiner, S
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 449 - CHED
[8] STRUCTURE OF 1,1'-BIS(DIPHENYLPHOSPHINOTETRAMETHYL)FERROCENE
TROUVE, G
BROUSSIER, R
GAUTHERON, B
KUBICKI, MM
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 1966 - 1967
[9] Electrochemistry of 1,1′-Bis(2,4-dialkylphosphetanyl)ferrocene and 1,1′-Bis(2,5-dialkylphospholanyl)ferrocene Ligands: Free Phosphines, Metal Complexes, and Chalcogenides
Mandell, Chelsea L.
Kleinbach, Shannon S.
Dougherty, William G.
Kassel, W. Scott
Nataro, Chip
INORGANIC CHEMISTRY, 2010, 49 (20) : 9718 - 9727
[10] MOLECULAR AND CRYSTAL-STRUCTURE OF "1,1'-BIS(PHENYLGLYOXYLOYL)FERROCENE
SZULZEWSKY, K
SEIDEL, I
KULPE, S
HOHNE, E
RAUBACH, H
STOFFER, U
KRISTALL UND TECHNIK-CRYSTAL RESEARCH AND TECHNOLOGY, 1979, 14 (01): : 37 - 45

← 1 2 3 4 5 →