Development, characterization and application of a low-cost single chamber microbial fuel cell based on hydraulic couplers

被引:25
|
作者
Silveira, Gustavo [1 ]
Neto, Sidney de Aquino [2 ]
Schneedorf, Jose Mauricio [3 ]
机构
[1] Univ Fed Alfenas Unifal MG, Fac Ciencias Farmaceut, Dept Alimentos & Medicamentos, BR-37130001 Alfenas, MG, Brazil
[2] Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
[3] Univ Fed Alfenas Unifal MG, Inst Ciencias Biomed, Dept Bioquim, BR-37130001 Alfenas, MG, Brazil
基金
巴西圣保罗研究基金会;
关键词
Single chamber microbial fuel cell; Solid-state cathodes; Hydraulic couplers; Saccharomyces cerevisiae; Prussian blue; WASTE-WATER TREATMENT; OXYGEN REDUCTION CATHODE; BLUE MODIFIED ELECTRODE; PRUSSIAN BLUE; ELECTRICITY-GENERATION; HYDROGEN-PEROXIDE; ENHANCED PERFORMANCE; BIOFUEL CELL; YEAST; ENERGY;
D O I
10.1016/j.energy.2020.118395
中图分类号
O414.1 [热力学];
学科分类号
摘要
The development of a low-cost and single chamber solid-state cathode microbial fuel cell is the main objective of this work. The architecture was built using hydraulic connections, an agar-KCI salt bridge, and Saccharomyces cerevisiae as the anodic bioelectrocatalyst. A Prussian blue film electrodeposited on carbon mesh support was employed as a cost-effective, solid-state cathode. Scanning electron microscopy images and energy dispersive spectra confirm the deposition of the Prussian blue on the cathode material. Cyclic voltammetry measurements of the modified electrode indicate a diffusion-limited process due to the intercalation of potassium ions in the Prussian blue structure. Oxi-reduction reactions leading by hydrogen peroxide allow the reactivation and renewal of the electrode after the operation of the microbial fuel cell. Polarization curves exhibit maximum power densities of 136 mW m(-2) using lyophilized yeast or 67 mW m(-2) using a brewery effluent, which demonstrates the feasibility for bioelectricity generation from this kind of wastewater. The single chamber microbial fuel cell under US$ 1 and constructed with hydraulic couplers can be an alternative for fuel cells of similar architecture. (C) 2020 Elsevier Ltd. All rights reserved.
引用
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页数:9
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