Direct Decomposition of N2O Emitted from Nitric Acid Plant Tail Gases Using Noble Metal Supported Mordenite-Zeolite Catalysts

被引:1
|
作者
Kwon, Byung-Chan [1 ]
Cho, Sung-Su [1 ]
Seo, Minhye [1 ]
Lee, Sungkyu [1 ]
Song, Jinho [1 ]
机构
[1] Adv Mat & Proc Ctr, Inst Adv Engn, Yongin, South Korea
关键词
FE-ZSM-5; CATALYSTS; REDUCTION; O-2;
D O I
10.3139/120.110440
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Mordenite based catalysts for direct decomposition of N2O have been successfully prepared and their direct decomposition performance characterized at the operating temperature of 300-400 degrees C commonly encountered in the nitric acid plants tail gases. The catalyst was prepared in 2 steps: 1. Precursor wet ion exchange, 2. Precursor impregnation. In addition to the previous contribution, it is shown here that the bimetallic Rh-, Pd-, Ir-Fe-MOR catalysts thus prepared exhibited an excellent N2O decomposition performance: total conversion efficiency of Rh-Fe-MOR catalyst has been achieved at 400 degrees C and between 7500 h(-1) and 10 000 h(-1) space velocity.
引用
收藏
页码:305 / 309
页数:5
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共 42 条
  • [1] Fabrication and Characterization of Bimetallic Mordenite-Zeolite Catalysts for Low Temperature Direct Decomposition of N2O Emitted from Nitric Acid Plants
    Seo, Minhye
    Cho, Sung-Su
    Kwyon, Byung-Chan
    Lee, Sungkyu
    [J]. MATERIALS TESTING, 2013, 55 (04) : 300 - 304
  • [2] New catalyst for removal of N2O from nitric acid plant tail gases
    Obalova, L.
    Kovanda, F.
    Jiratova, K.
    Sramek, J.
    Karaskova, K.
    Chromcakova, Z.
    Borovec, K.
    Dej, M.
    [J]. PROCEEDINGS OF THE 1ST INTERNATIONAL CONFERENCE ON CHEMICAL TECHNOLOGY, 2013, : 319 - 324
  • [3] Advances in Catalytic Decomposition of N2O by Noble Metal Catalysts
    Zhang, Yong
    Tian, Zhigao
    Huang, Lin
    Fan, Honghong
    Hou, Qiufei
    Cui, Ping
    Wang, Wanqiang
    [J]. CATALYSTS, 2023, 13 (06)
  • [4] Catalytic removal of N2O in model flue gases of a nitric acid plant using a promoted Fe zeolite
    van den Brink, RW
    Booneveld, S
    Pels, JR
    Bakker, DF
    Verhaak, MJFM
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2001, 32 (1-2) : 73 - 81
  • [5] Metal Exchanged ZSM-5 Zeolite Based Catalysts for Direct Decomposition of N2O
    Kumar, Suresh
    Rayalu, S.
    Russo, Nunzio
    Kanade, G. S.
    Kusaba, H.
    Teraoka, Y.
    Labhsetwar, Nitin
    [J]. CATALYSIS LETTERS, 2009, 132 (1-2) : 248 - 252
  • [6] Metal Exchanged ZSM-5 Zeolite Based Catalysts for Direct Decomposition of N2O
    Suresh Kumar
    S. Rayalu
    Nunzio Russo
    G. S. Kanade
    H. Kusaba
    Y. Teraoka
    Nitin Labhsetwar
    [J]. Catalysis Letters, 2009, 132 : 248 - 252
  • [7] Recent Advances in Catalytic Decomposition of N2O on Noble Metal and Metal Oxide Catalysts
    Liu, Zhiming
    He, Fang
    Ma, Lingling
    Peng, Sha
    [J]. CATALYSIS SURVEYS FROM ASIA, 2016, 20 (03) : 121 - 132
  • [8] Recent Advances in Catalytic Decomposition of N2O on Noble Metal and Metal Oxide Catalysts
    Zhiming Liu
    Fang He
    Lingling Ma
    Sha Peng
    [J]. Catalysis Surveys from Asia, 2016, 20 : 121 - 132
  • [9] Superior performance of ex-framework FeZSM-5 in direct N2O decomposition in tail-gases from nitric acid plants
    Pérez-Ramírez, J
    Kapteijn, F
    Mul, G
    Moulijn, JA
    [J]. CHEMICAL COMMUNICATIONS, 2001, (08) : 693 - 694
  • [10] Metal phosphate-supported RuOx catalysts for N2O decomposition
    Cui, Yuewei
    Liu, Huan
    Lin, Yi
    Ma, Zhen
    [J]. JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2016, 67 : 254 - 262