Preparation of mesoporous graphene oxide/SBA-15 hybrid nanoparticles as a potential adsorbent for removal of cationic dyes

被引:9
|
作者
Liou, Tzong-Horng [1 ,2 ]
Lin, Ming-Hui [1 ]
机构
[1] Ming Chi Univ Technol, Dept Chem Engn, 84 Gungjuan Rd, New Taipei 24301, Taiwan
[2] Ming Chi Univ Technol, Battery Res Ctr Green Energy, 84 Gungjuan Rd, New Taipei 24301, Taiwan
关键词
Graphene oxide; SBA-15; Mesostructure; Nanocomposite; Cationic dye; ADSORPTION PERFORMANCE; MECHANICAL-PROPERTIES; EFFICIENT ADSORPTION; CARBON COMPOSITE; AQUEOUS REMOVAL; METHYLENE-BLUE; CONGO RED; OXIDE; SBA-15; DEGRADATION;
D O I
10.5004/dwt.2019.24055
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this paper, mesoporous graphene oxide/SBA-15 nanocomposite was used as an adsorbent for removing cationic dyes from wastewater. Adsorption experiments tested the initial concentration of dye, calcination temperature, and pH of dye solution. The features of the composite were examined through X-ray diffractometry, field-emission scanning electron microscopy, transmission electron microscopy, Raman spectrometry, Fourier transform infrared spectrometer, and surface area analysis. The graphene oxide/SBA-15 samples possessed a high degree of oxidation that gave the composite an excellent adsorptive property toward dye. Higher solution pH and initial concentration of dye favored methylene blue adsorption. Adsorption capacity was highest at a calcination temperature of 550 degrees C. Adsorption kinetics and isotherms were analyzed. The adsorption process was well fitted by the pseudo- second order kinetic model and Langmuir isotherm model. The mesoporous graphene oxide/SBA15 composite is a promising material for removing aqueous organic pollutants.
引用
收藏
页码:285 / 295
页数:11
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