An alkaline-resistant Ag(I)-anchored pyrazolate-based metal-organic framework for chemical fixation of CO2

被引：54
|
作者：
Yang, Huimin [1 ]
Zhang, Xu [1 ]
Zhang, Guiyang [1 ]
Fei, Honghan [1 ]
机构：
[1] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 35期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE; EFFICIENT; CAPTURE; CATALYST; CONVERSION; CHEMISTRY; AMINES; LIGAND;
D O I：
10.1039/c8cc01461b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An alkaline-resistant Ag(I)-anchored metal-organic framework has been achieved via postsynthetic modification of pyrazolate-based linkers. For the first time, the resultant MOF was completely heterogeneous and recyclable over at least ten cycles in cyclic carboxylation of propargyl amines and CO2 into oxazolidinones and tetramic acids under atmospheric pressure of CO2.
引用
收藏
页码：4469 / 4472
页数：4
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