Enantioselective Functionalization of Terminal Alkynes by Gold Catalysis

被引：19
|
作者：
Mourad, Asmaa Kamal [1 ,2 ]
Czekelius, Constantin [1 ]
机构：
[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
[2] Fayoum Univ, Al Fayyum 63514, Egypt
来源：
SYNLETT | 2013年 / 24卷 / 12期
关键词：
alkynes; asymmetric catalysis; gold; isomerization; desymmetrization; DIAMINOCARBENE COMPLEXES; MECHANISTIC INSIGHTS; ASYMMETRIC-SYNTHESIS; CHIRAL ANIONS; REARRANGEMENT; CYCLIZATIONS; SILVER; CYCLOISOMERIZATION; 2-CYCLOPENTENONES; HYDROAMINATION;
D O I：
10.1055/s-0033-1338841
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enantioselective functionalization of alkynes is still a challenge in the field of gold catalysis. This article describes recent progress in the application of gold complexes with optically active ligands or counteranions for activation of alkynes towards nucleophiles, including the recently reported desymmetrization of terminal diynes.
引用
收藏
页码：1459 / 1463
页数：5
相关论文
共 50 条
  • [1] Enantioselective functionalization of terminal alkynes by gold catalysis
    Czekelius, Constantin
    Mourad, Asmaa K.
    Leutzow, Juliane
    Ruettinger, Roman
    Wilckens, Kristina
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [2] Enantioselective C-H Functionalization Reactions under Gold Catalysis
    Das, Avishek
    Patil, Nitin T.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (20)
  • [3] Gold-Catalyzed Functionalization of Semicarbazides with Terminal Alkynes to Achieve Substituted Semicarbazones
    Zimin, Dmitry P.
    Dar'in, Dmitry, V
    Eliseeva, Anastasiya A.
    Novikov, Alexander S.
    Rassadin, Valentin A.
    Kukushkin, Vadim Yu
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 2019 (35) : 6094 - 6100
  • [4] Regio- and Enantioselective Allylic Alkylation of Terminal Alkynes by Synergistic Rh/Cu Catalysis
    Huang, Wen-Yu
    Lu, Chun-Hua
    Ghorai, Samir
    Li, Bing
    Li, Changkun
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (36) : 15276 - 15281
  • [5] Enantioselective Double Manipulation of Tetrahydroisoquinolines with Terminal Alkynes and Aldehydes under Copper(I) Catalysis
    Lin, Weilong
    Cao, Tao
    Fan, Wu
    Han, Yulin
    Kuang, Jinqiang
    Luo, Hongwen
    Miao, Bukeyan
    Tang, Xinjun
    Yu, Qiong
    Yuan, Weiming
    Zhang, Jiasheng
    Zhu, Can
    Ma, Shengming
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (01) : 277 - 281
  • [6] Regio- and Enantioselective Allylic Alkylation of Terminal Alkynes by Synergistic Rh/Cu Catalysis
    Huang, Wen-Yu
    Lu, Chun-Hua
    Ghorai, Samir
    Li, Bing
    Li, Changkun
    [J]. SYNTHESIS-STUTTGART, 2021, 53 (01): : A11 - A14
  • [7] Co/Zn Bimetallic Catalysis Enables Enantioselective Alkynylation of Isatins and α-Ketoesters Using Terminal Alkynes
    Huang, Rui-Zhi
    Ma, Zhan-Cai
    Huang, Yuan
    Zhao, Yu
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2022, 88 (12): : 7755 - 7763
  • [8] Enantioselective redox gold catalysis
    Chetan C. Chintawar
    Nitin T. Patil
    [J]. Gold Bulletin, 2022, 55 : 161 - 168
  • [9] Enantioselective redox gold catalysis
    Chintawar, Chetan C.
    Patil, Nitin T.
    [J]. GOLD BULLETIN, 2022, 55 (02) : 161 - 168
  • [10] Recent advances in the functionalization of terminal and internal alkynes
    Ramani, Arti
    Desai, Bhargav
    Patel, Monak
    Naveen, Togati
    [J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (05)
12345