A regio- and stereoselective platinum(0)-catalyzed hydroboration of allenes controlled by phosphine ligands

被引：59
|
作者：
Yamamoto, Y [1 ]
Fujikawa, R [1 ]
Yamada, A [1 ]
Miyaura, N [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 10期
关键词：
D O I：
10.1246/cl.1999.1069
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydroboration of terminal allenes with pinacolborane was carried out at 50 degrees C in the presence of a Pt(dba)(2)/2PR(3) catalyst The formation of one of three possible monohydroboration products was regioselectively synthesized by choosing an appropriate phosphine ligand.
引用
收藏
页码：1069 / 1070
页数：2
相关论文
共 50 条
  • [1] Cobalt-Catalyzed Regio- and Stereoselective Hydroboration of Allenes
    Li, Can
    Yang, Zheng
    Wang, Lei
    Guo, Yinlong
    Huang, Zheng
    Ma, Shengming
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (15) : 6278 - 6283
  • [2] Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Hydroboration of Allenes
    Zhu, Can
    Yang, Bin
    Qiu, Youai
    Backvall, Jan-E.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (09) : 2939 - 2943
  • [3] Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes
    Jeganmohan, M
    Shanmugasundaram, M
    Chang, KJ
    Cheng, CH
    [J]. CHEMICAL COMMUNICATIONS, 2002, (21) : 2552 - 2553
  • [4] Regio- and Stereoselective Oxysulfonylation of Allenes
    Huang, Zhiyuan
    Lu, Qingquan
    Liu, Yichang
    Liu, Dong
    Zhang, Jian
    Lei, Aiwen
    [J]. ORGANIC LETTERS, 2016, 18 (16) : 3940 - 3943
  • [5] Copper(I)-Catalyzed Regio- and Stereoselective Silaboration of Terminal Allenes
    Ozawa, Yu
    Koriyama, Hisao
    Shiratori, Yuma
    Ito, Hajime
    [J]. ACS ORGANIC & INORGANIC AU, 2023, 3 (02): : 104 - 108
  • [6] Regio- and Stereoselective Au(I)-Catalyzed Intermolecular Hydroalkoxylation of Aryl Allenes
    Cui, Dong-Mei
    Yu, Ke-Rui
    Zhang, Chen
    [J]. SYNLETT, 2009, (07) : 1103 - 1106
  • [7] Regio- and stereoselective synthesis of allylboranes via platinum(0)-catalyzed borylation of allyl halides with pinacolborane
    Murata, M
    Watanabe, S
    Masuda, Y
    [J]. TETRAHEDRON LETTERS, 2000, 41 (31) : 5877 - 5880
  • [8] Regio- and Stereoselective Cobalt-Catalyzed Hydroboration of Vinylcyclopropanes to Access Homoallylic Boronates
    Lu, Dongpo
    Chen, Chenhui
    Zheng, Lixuan
    Ying, Jiale
    Lu, Zhan
    [J]. ORGANOMETALLICS, 2023, 42 (14) : 1699 - 1703
  • [9] Palladium-catalyzed hydrophosphorylation of allenes leading to regio- and stereoselective formation of allylphosphonates
    Zhao, CQ
    Han, LB
    Tanaka, M
    [J]. ORGANOMETALLICS, 2000, 19 (21) : 4196 - 4198
  • [10] Cu-catalyzed regio- and stereoselective sulfonylation of multi-substituted allenes
    Arai, Shigeru
    Matsumoto, Koki
    Nishida, Atsushi
    [J]. TETRAHEDRON, 2019, 75 (09) : 1145 - 1148
12345