OXIDATION OF OXIMES USING POTASSIUM PERMANGANATE SUPPORTED ON ALUMINUM SILICATE UNDER SOLVENT-FREE CONDITIONS

被引：0

作者：

Lou, Ji-Dong ^{[1
,2
]}

Lin, Fang ^{[1
]}

Zhang, Changhe ^{[3
]}

Zhu, Li-Yun ^{[1
]}

Lin, Jianan ^{[1
]}

机构：

[1] China Jiliang Univ, Coll Life Sci, Hangzhou 310018, Zhejiang, Peoples R China

[2] Sirnaomics Inc, Gaithersburg, MD 20879 USA

[3] UTAD, Ctr Res & Technol Agroenvironm & Biol Sci CITAB, Dept Biol & Environm, P-5001801 Vila Real, Portugal

来源：

OXIDATION COMMUNICATIONS | 2013年 / 36卷 / 02期

关键词：

aldehydes; aluminum silicate; ketones; oxidation; oximes; potassium permanganate; ENVIRONMENTALLY BENIGN PROCEDURE; GRAPHITE REAGENT; CLEAVAGE; MILD; DEOXIMATION; CONVERSION; ALCOHOLS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and efficient oxidation of oximes to the corresponding ketones and aldehydes with potassium permanganate supported on aluminum silicate under solvent-free conditions at room temperature in the yields between 80 and 95 is described. The main advantages of the present method are the enhanced oxidation selectivity and reactivity, mild reaction conditions, and straightforward work-up procedure.

引用

页码：492 / 496

页数：5

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