P-N-S/Se-containing metallacycles

被引：129
|
作者：
Woollins, JD
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 14期
关键词：
D O I：
10.1039/dt9960002893
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M{(Pr2P)-P-1(S)NP(S)Pr-2(1)}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.
引用
收藏
页码：2893 / &
页数：10
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