Sol-gel synthesis of SnO2-MgO nanoparticles and their photocatalytic activity towards methylene blue degradation

SnO2-MgO mixed metal oxide nanoparticles were prepared by a simple sol-gel method. The nanoparticles were characterized by power X-ray diffraction, scanning electron microscopy coupled with energy dispersive X-ray analysis, transmission electron microscopy and UV-vis diffuse reflectance spectroscopy. The XRD results indicate the formation of mixed metal oxide nanoparticles and also a decrease of SnO2 crystallite size in the mixed metal oxide nanoparticles with increasing magnesium oxide content. The reflectance spectroscopy results show a blue shift of the band gap of SnO2 in the mixed metal oxide nanoparticles. The photocatalytic activity of the SnO2-MgO nanoparticles was tested using the photodegradation of aqueous methylene blue in the presence of sunlight. The results indicate that the mixed metal oxide nanoparticles possess higher efficiency for the photodegradation of methylene blue compared to pure SnO2 nanoparticles. (c) 2013 Elsevier Ltd. All rights reserved.