EPDM Rubber Modified by Nitrogen Plasma Immersion Ion Implantation

被引：12
|
作者：
Kondyurin, Alexey [1 ]
机构：
[1] Univ Sydney, Sch Phys, Sydney, NSW 2006, Australia
来源：
MATERIALS | 2018年 / 11卷 / 05期
关键词：
ethylene-propylene diene monomer rubber EPDM; plasma immersion ion implantation; adhesion; FTIR ATR; interface; polyurethane; HEAT SHIELDING MATERIALS; SURFACE MODIFICATION; ROCKET MOTORS; ADHESION; COMPOSITES; IRRADIATION; IMPROVEMENT; POLYMERS; ENERGY;
D O I：
10.3390/ma11050657
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ethylene-propylene diene monomer rubber (EPDM) was treated by plasma immersion ion implantation (PIII) with nitrogen ions of 20 keV energy and fluence from 10(13) to 10(16) ions/cm(2). The Fourier-transform infrared attenuated total reflection spectra, atomic force microscopy and optical microscopy showed significant structure changes of the surface. The analysis of an interface of PIII treated EPDM rubber with polyurethane binder showed a cohesive character of the adhesion joint fracture at the presence of solvent and interpreted as covalent bond network formation between the PIII treated rubber and the adhesive.
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页数：16
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