Iron-catalyzed aerobic difunctionalization of alkenes: a highly efficient approach to construct oxindoles by C-S and C-C bond formation

被引：157

作者：

Shen, Tao ^{[1
]}

Yuan, Yizhi ^{[1
]}

Song, Song ^{[1
]}

Jiao, Ning ^{[1
,2
]}

机构：

[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 31期

基金：

美国国家科学基金会;

关键词：

ACTIVATED ALKENES; CARBOCYCLIZATION; ROUTE;

D O I：

10.1039/c4cc00401a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel iron-catalyzed efficient approach to construct sulfonecontaining oxindoles, which play important roles in the structural library design and drug discovery, has been developed. The use of readily available benzenesulfinic acids, an inexpensive iron salt as the catalyst, and air as the oxidant makes this sulfur incorporation protocol very efficient and practical.

引用

页码：4115 / 4118

页数：4

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