Catalytic Ozonation of Alkylnaphthalenes in Acetic Acid

被引：1
|
作者：
Potapenko, E. V. [1 ]
机构：
[1] Dal E Ukrainian Natl Univ, Inst Chem Technol, Rubezhnoye, Lugansk Oblast, Ukraine
来源：
KINETICS AND CATALYSIS | 2012年 / 53卷 / 01期
关键词：
OXIDATION;
D O I：
10.1134/S0023158412010089
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxidation of alkylnaphthalenes with ozone in acetic acid in the presence of cobalt(II) acetate is reported. Under the catalytic conditions, the ozonolysis of the aromatic system can be prevented to a considerable extent and the reaction can be directed toward the oxidation of the alkyl group. The kinetics of the main steps of the process is reported, and the mechanism of redox catalysis is presented.
引用
收藏
页码：36 / 41
页数：6
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