Multifunctionalized porosity in zeolitic diamondoid porous organic salt: selective adsorption and guest-responsive fluorescent properties

被引：42

作者：

Yamamoto, Atsushi ^{[1
]}

Hirukawa, Tomofumi ^{[1
]}

Hisaki, Ichiro ^{[1
]}

Miyata, Mikiji ^{[1
]}

Tohnai, Norimitsu ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

[2] Japan Sci & Technol Agcy JST, Kawaguchi, Saitama 3320012, Japan

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 10期

基金：

日本学术振兴会;

关键词：

Porous structure; Organic salt; Supramolecular cluster; Luminescence; Diamondoid network; CARBON-DIOXIDE CAPTURE; RETICULAR SYNTHESIS; CRYSTAL; INCLUSION; POLYMERIZATION; CONSTRUCTION; ANTHRACENE; DESIGN;

D O I：

10.1016/j.tetlet.2012.12.086

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An organic salt composed of triphenylmethylamine and a fluorescent disulfonic acid provides a diamondoid porous organic salt (d-POS) through formation of connectable tetrahedral supramolecular clusters. The d-POS completely keeps its open channel structure upon guest desorption and adsorption and shows not only zeolitic property such as selective gas and molecular adsorption but also tunable fluorescent property in response to adsorbed molecules. The fluorescent color is changed from blue to green by incorporating electron-donor molecules while the fluorescence is quenched by electron-acceptor molecules. These results demonstrate efficient usability of the design for constructing functional rigid porous structures. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：1268 / 1273

页数：6

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