Syntheses and structures of 1D, 2D, 3D cadmium(II) coordination polymers with oxalate and aromatic co-ligands

被引：55

作者：

Xia, SQ ^{[1
]}

Hu, SM ^{[1
]}

Dai, JC ^{[1
]}

Wu, XT ^{[1
]}

Fu, ZY ^{[1
]}

Zhang, HJ ^{[1
]}

Du, WX ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

POLYHEDRON | 2004年 / 23卷 / 06期

基金：

美国国家科学基金会;

关键词：

cadmium; coordinate; polymers; ligands; supramolecular;

D O I：

10.1016/j.poly.2003.12.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four mixed-ligand complexes, {Na-2[Cd-2(Htma)(2)(ox)(H2O)(2)]}(n)(1) (tma = trimesate, ox = oxalate), {[Cd-2(2,2'-bipyridine)(2)(ox)(2)](.)2H(2)O}(n) (2), {Cd-3(4,4'-trimethylenedipyridine)(3)(ox)(3)}(n) (3), and {Na-2[Cd-4(isonicotinate)(4)(ox)(3)]}(n) (4) were synthesized by hydrothermal reactions. The structures of 1, 2, 3 and 4 consist of 1D ladder-like chains, 1D zigzag chains, a 2D square network and a 3D framework, respectively, featuring dinuclear (for 1 and 2), trinuclear (for 3) and tetranuclear (for 4) units. The TGA experiments showed that these four complexes were quite thermally stable. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1003 / 1009

页数：7

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