Acid-catalyzed formation of hexahomooxacalix[3]arenes

被引：10

作者：

Miah, M

Romanov, NN

Cragg, PJ ^{[1
]}

机构：

[1] Univ Brighton, Sch Pharm & Biomol Sci, Brighton BN2 4GJ, E Sussex, England

[2] Ukrainian Acad Sci, Inst Organ Chem, UA-253660 Kiev, Ukraine

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 09期

关键词：

D O I：

10.1021/jo025597a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The role of acid catalysis in oxacalix[3]arene synthesis has been investigated, A range of acids were used to optimize the yield of tert-butyloxacalix[3]arene, the most efficient being p-toluenesulfonic acid, which, with local symmetry complementary with that of the lower rim of the calixarene, provides a templating effect.

引用

页码：3124 / 3126

页数：3

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