A new approach to the synthesis of functional derivatives of nido-carborane: alkylation of [9-MeS-nido-7,8-C2B9H11]-

被引：23

作者：

Zakharova, Maria V. ^{[1
]}

Sivaev, Igor B. ^{[1
]}

Anufriev, Sergey A. ^{[1
]}

Timofeev, Sergey V. ^{[1
]}

Suponitsky, Kyrill Yu ^{[1
]}

Godovikov, Ivan A. ^{[1
]}

Bregadze, Vladimir I. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 13期

基金：

俄罗斯基础研究基金会;

关键词：

NEUTRON-CAPTURE THERAPY; MOLECULAR-STRUCTURE; SULFIDE DERIVATIVES; FLUORIDE-ION; CHEMISTRY; CRYSTAL; BORANES; ANION; SALT; NMR;

D O I：

10.1039/c3dt52845f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of asymmetrically substituted sulfonium derivatives of nido-carborane [9-R(Me)S-nido-7,8-C2B9H11] (R = Et, Pr, Bu, Bn, CH=CH2, CH2CH=CH2, CH2C equivalent to CH, CH=C=CH2) were prepared by alkylation of the 9-methylthio-nido-7,8-carborane. The synthesized compounds are the first examples of diastereomers combining nido-carborane and sulfonium chiral centers.

引用

页码：5044 / 5053

页数：10

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