Emerging Organic Photoredox Catalysts for Organic Transformations

被引:109
|
作者
Lee, Yungyeong [2 ]
Kwon, Min Sang [1 ]
机构
[1] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 08826, South Korea
[2] Ulsan Natl Inst Sci & Technol UNIST, Dept Mat Sci & Engn, Ulsan 44919, South Korea
关键词
Catalyst design; Organic photocatalysts; Photochemistry; Photoredox catalysis; TRANSFER RADICAL POLYMERIZATION; VISIBLE-LIGHT PHOTOCATALYSIS; GRAPHITIC CARBON NITRIDE; N-ARYL PHENOXAZINES; PET-RAFT; EOSIN Y; DESIGN; DRIVEN; MECHANISM; ACIDS;
D O I
10.1002/ejoc.202000720
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A lot of efforts have been made for the development of novel organic photoredox catalysts (PCs) due to their gratifying replacement for conventional transition metal-based PCs in photoredox catalysis. In this minireview, we summarized and classified the recently reported organic PCs into several categories based on functional groups (e.g. cyanoarene, phenazine, xanthene, and others) with their applications to various organic transformations including polymerization reactions. The strategies used to design organic PCs then also introduced. The emerging trends for the discovery of organic PCs are systematic approaches which include computer-aided and mechanism-based design. We anticipate that this minireview will provide not only the characteristics of the recently reported organic PCs, but also an insight into the design and discovery of organic PCs for desired applications.
引用
收藏
页码:6028 / 6043
页数:16
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