Separation of platinum(IV) and palladium(II) from concentrated hydrochloric acid solutions by mixtures of amines with neutral extractants

被引：70
|
作者：
Thi Hong Nguyen [1 ]
Sonu, Chong Ho [2 ]
Lee, Man Seung [1 ]
机构：
[1] Mokpo Natl Univ, Inst Rare Met, Dept Adv Mat Sci & Engn, Chungnam 534729, South Korea
[2] LS Nikko Copper Inc, Metall Resources Technol Lab, Kyunggi 463400, South Korea
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2015年 / 32卷
关键词：
Platinum; Palladium; Hydrochloric acid; Separation; Solvent extraction; SOLVENT-EXTRACTION; CHLORIDE SOLUTIONS; RECOVERY; RHODIUM; PT(IV); RH(III); PD(II); GOLD;
D O I：
10.1016/j.jiec.2015.08.022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Separation of platinum and palladium from concentrated HCl solutions by extraction with mixture of amines (Aliquat 336/Alamine 336/TOA) and neutral extractants (TBP/TOP/MIBK) have been investigated. The mixture of Aliquat 336 and TBP led to higher Pt(IV) separation factor at 6 M HCl solution. McCabe-Thiele diagram for the extraction of Pt by this mixture was constructed. Low concentration of thiourea in the HCl solution resulted in selective stripping of Pd from the loaded organic. Pt solution with 99.9% purity was obtained by extraction and stripping from the solution containing Pd. A process was proposed to separate the two metals. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：238 / 245
页数：8
相关论文
共 50 条
  • [1] Sorption Recovery of Palladium (II) and Platinum (IV) from Hydrochloric Acid Solutions
    Kononova, Olga N.
    Duba, Evgeniya V.
    Schneider, Nikita I.
    Pozdnyakov, Iliya A.
    JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2018, 11 (01): : 6 - 17
  • [2] Extraction of palladium(II), platinum(II), and platinum(IV) by bisacylated diethylenetriamine from hydrochloric acid solutions
    Khisamutdinov, R. A.
    Bondareva, S. O.
    Murinov, Yu. I.
    Baikova, I. P.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (03) : 462 - 469
  • [3] Extraction of Palladium(II), Platinum(II), and Platinum(IV) by Bisacylated Diethylenetriamine from Hydrochloric Acid Solutions
    R. A. Khisamutdinov
    S. O. Bondareva
    Yu. I. Murinov
    I. P. Baikova
    Russian Journal of Inorganic Chemistry, 2008, 53 : 462 - 469
  • [4] Rapid separation of palladium(II) from platinum(IV) in hydrochloric acid solution with thiodiglycolamide
    Narita, H
    Tanaka, M
    Morisaku, K
    Abe, T
    CHEMISTRY LETTERS, 2004, 33 (09) : 1144 - 1145
  • [5] Ion exchange extraction of platinum(IV) and palladium(II) from hydrochloric acid solutions
    Kononova, O. N.
    Duba, E. V.
    Shnaider, N. I.
    Pozdnyakov, I. A.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2017, 90 (08) : 1239 - 1245
  • [6] Ion exchange extraction of platinum(IV) and palladium(II) from hydrochloric acid solutions
    O. N. Kononova
    E. V. Duba
    N. I. Shnaider
    I. A. Pozdnyakov
    Russian Journal of Applied Chemistry, 2017, 90 : 1239 - 1245
  • [7] Selective extraction of palladium(II) from hydrochloric acid solutions with phosphonium extractants
    Cieszynska, A.
    Wisniewski, M.
    SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 80 (02) : 385 - 389
  • [8] Solvent extraction and separation of palladium(II) and platinum(IV) from hydrochloric acid medium with dibutyl sulfoxide
    Pan, Lu
    Zhang, Zu-de
    MINERALS ENGINEERING, 2009, 22 (15) : 1271 - 1276
  • [9] INVESTIGATION OF POSSIBLE INTERACTIONS BETWEEN PALLADIUM(II) AND PALLADIUM(IV) AND BETWEEN PALLADIUM(II) AND PLATINUM(IV) IN HYDROCHLORIC ACID SOLUTIONS AND IN THE CRYSTALLINE STATE
    COHEN, AJ
    DAVIDSON, N
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (05) : 1955 - 1958
  • [10] Solvent Extractive Separation of Zirconium and Hafnium from Hydrochloric Acid Solutions by Organophosphorous Extractants and Their Mixtures with Other Types of Extractants
    Wang, L. Y.
    Lee, H. Y.
    Lee, M. S.
    CHEMICAL ENGINEERING COMMUNICATIONS, 2015, 202 (10) : 1289 - 1295
12345