Transitions between paraelectric and ferroelectric phases of bent-core smectic liquid crystals in the bulk and in thin freely suspended films

被引:19
|
作者
Eremin, Alexey [1 ]
Floegel, Martin [1 ]
Kornek, Ulrike [1 ]
Stern, Stephan [1 ]
Stannarius, Ralf [1 ]
Nadasi, Hajnalka [2 ]
Weissflog, Wolfgang [2 ]
Zhu, Chenhui [3 ,4 ]
Shen, Yongqiang [3 ,4 ]
Park, Cheol Soo [3 ,4 ]
Maclennan, Joseph [3 ,4 ]
Clark, Noel [3 ,4 ]
机构
[1] Univ Magdeburg, Inst Expt Phys, ANP, D-39016 Magdeburg, Germany
[2] Univ Halle Wittenberg, Inst Phys Chem, D-06120 Halle, Saale, Germany
[3] Univ Colorado, Dept Phys, Boulder, CO 80309 USA
[4] Univ Colorado, Liquid Crystal Mat Res Ctr, Boulder, CO 80309 USA
来源
PHYSICAL REVIEW E | 2012年 / 86卷 / 05期
关键词
SUPERSTRUCTURAL CHIRALITY; POLAR ORDER; POLARIZATION; PATTERNS; FIELD;
D O I
10.1103/PhysRevE.86.051701
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We report on the contrasting phase behavior of a bent-core liquid crystal with a large opening angle between the mesogenic units in the bulk and in freely suspended films. Second-harmonic generation experiments and direct observation of director inversion walls in films in an applied electric field reveal that the nonpolar smectic C phase observed in bulk samples becomes a ferroelectric "banana" phase in films, showing that a mesogen with a small steric moment can give a phase with polar order in freely suspended films even when the corresponding bulk phase is paraelectric.
引用
收藏
页数:10
相关论文
共 50 条
  • [1] Layer structures of ferroelectric smectic liquid crystals formed by bent-core molecules
    Jákli, A
    Lischka, C
    Weissflog, W
    Rauch, S
    Heppke, G
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 328 : 299 - 307
  • [2] Layer Structures of Ferroelectric Smectic Liquid Crystals Formed by Bent-Core Molecules
    Ctrl. Res. Inst. Solid Stt. Phys. O., P.O. Box 49, H-1525 Budapest, Hungary
    不详
    不详
    Mol Cryst Liq Cryst Sci Technol Sect A Mol Crys Liq Cryst, (299-307):
  • [3] The Nematic Phases of Bent-Core Liquid Crystals
    Gleeson, Helen F.
    Kaur, Sarabjot
    Goertz, Verena
    Belaissaoui, Abdel
    Cowling, Stephen
    Goodby, John W.
    CHEMPHYSCHEM, 2014, 15 (07) : 1251 - 1260
  • [4] Dimensional Reduction for the Ferroelectric Smectic A-Type Phase of Bent-Core Liquid Crystals
    Garcia-Cervera, Carlos J.
    Giorgi, Tiziana
    Joo, Sookyung
    JOURNAL OF NONLINEAR SCIENCE, 2023, 33 (01)
  • [5] Dimensional Reduction for the Ferroelectric Smectic A-Type Phase of Bent-Core Liquid Crystals
    Carlos J. García-Cervera
    Tiziana Giorgi
    Sookyung Joo
    Journal of Nonlinear Science, 2023, 33
  • [6] Azo-containing asymmetric bent-core liquid crystals with modulated smectic phases
    Trisovic, Nemanja
    Antanasijevic, Jelena
    Toth-Katona, Tibor
    Kohout, Michal
    Salamonczyk, Miroslaw
    Sprunt, Samuel
    Jakli, Antal
    Fodor-Csorba, Katalin
    RSC ADVANCES, 2015, 5 (80): : 64886 - 64891
  • [7] Structural transitions of smectic phases formed by achiral bent-core molecules
    Jákli, A
    Lischka, C
    Weissflog, W
    Pelzl, G
    Rauch, S
    Heppke, G
    FERROELECTRICS, 2000, 243 (1-4) : 239 - +
  • [8] Dark conglomerate phases of bent-core liquid crystals
    Nagaraj, M.
    LIQUID CRYSTALS, 2016, 43 (13-15) : 2244 - 2253
  • [9] Orientation control over bent-core smectic liquid crystal phases
    Kim, Hanim
    Kim, Yun Ho
    Lee, Sunhee
    Walba, David M.
    Clark, Noel A.
    Lee, Sang Bok
    Yoon, Dong Ki
    LIQUID CRYSTALS, 2014, 41 (03) : 328 - 341
  • [10] Paraelectric-antiferroelectric transitions in the bent-core liquid-crystalline materials
    Eremin, A
    Nádasi, H
    Pelzl, G
    Diele, S
    Kresse, H
    Weissflog, W
    Grande, S
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (06) : 1290 - 1298