Isomorphous Substitution and Luminescence Properties of Haloapatites Synthesized by the Low-Temperature Method

被引：0
|
作者：
Savin, Yu. N. [1 ]
Babayevskaya, N. V. [1 ]
Tolmachev, A. V. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Sci Tech Ctr, Inst Single Crystals, UA-61001 Kharkov, Ukraine
来源：
CRYSTALLOGRAPHY REPORTS | 2008年 / 53卷 / 07期
关键词：
D O I：
10.1134/S1063774508070274
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single-phase polycrystalline fluorapatites of the Ca(10-x)Me(x)(PO(4))(6)F(2):Eu(3+) (Me = Pb, Mg) composition are obtained by deposition from aqueous solutions. The effect of modifier ions (Pb(2+), Mg(2+)) with significantly different ionic radii on the structure and spectral luminescence properties of the fluorapatites are studied. It is established that Pb(2+) and Mg(2+) ions affect the preferred location of Eu(3+) ions in the structure of Ca(10-x)Me(x)(PO(4))(6)F(2) crystals.
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收藏
页码：1256 / 1260
页数：5
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