A simple and highly selective biomimetic oxidation of alcohols and epoxides with N-bromosuccinimide in the presence of β-cyclodextrin in water

被引：96

作者：

Krishnaveni, NS ^{[1
]}

Surendra, K ^{[1
]}

Rao, KR ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div I, Hyderabad 500007, Andhra Pradesh, India

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 2-3期

关键词：

alcohols; biomimetic; N-bromosuccinimide; beta-cyclodextrin; epoxides; oxidation; water;

D O I：

10.1002/adsc.200303164

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A simple, mild and highly efficient biomimetic oxidation of various alcohols and epoxides with N-bromosuccinimide (NBS) catalyzed by beta-cyclodextrin in water has been developed. A series of alcohols and epoxides were oxidized selectively at room temperature in excellent yields. This method is a direct one-pot synthesis under mild conditions using water as solvent and has many advantages over the existing methodologies.

引用

页码：346 / 350

页数：5

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