Syntheses, structures and properties of Mn(II), Zn(II) and Ag(I) coordination polymers with 2-(1,2,4-triazol-1-yl)acetate

被引：8

作者：

Qian, Xin ^{[1
]}

Sun, Peng-Peng ^{[1
]}

Ding, Jian-Gang ^{[1
]}

Li, Bao-Long ^{[1
]}

Li, Han-Yan ^{[1
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1031卷

关键词：

CdCl2-type topology; Coordination polymer; Luminescence; Two-dimensional network; TG and UV; METAL-ORGANIC FRAMEWORK; BUILDING-BLOCKS; CRYSTAL; LIGAND; ENTANGLEMENT; NETWORKS; CLUSTER; NETS; 1D; 2D;

D O I：

10.1016/j.molstruc.2012.07.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The self-assembly reaction of 2-(1,2,4-triazol-1-yl)acetic acid (Htza) with Mn(II), Zn(II) and Ag(I) salts gave three coordination polymers [Mn(tza)(2)](n) (1), [Zn(tza)(2)](n) (2) and [Ag-3(tza)(2)(ClO4)](n) (3). 1 has a (3,6)-connected CdCl2-type two-dimensional network. 2 is a neutral two-dimensional (4,4) network. However 3 shows the complicated two-dimensional undulated network. 2 and 3 exhibit blue luminescent emissions maxima at 420 and 437 nm, respectively in the solid state at room temperature. The thermal stability of 1, 2 and 3 were observed. The diffuse reflectance UV-vis spectroscopy of 1, 2 and 3 were measured. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：175 / 179

页数：5

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