Chemical synthesis and characterization of soluble conducting poly(2-aminothiazole)

被引：23
|
作者：
Biyikoglu, Mutluhan [1 ]
Ciftci, Hakan [2 ]
机构：
[1] Kirikkale Univ, Fac Art & Sci, Dept Chem, TR-71450 Yahsihan, Kirikkale, Turkey
[2] Kirikkale Univ, Kirikkale Vocat High Sch, Dept Chem & Chem Proc Technol, TR-71450 Yahsihan, Kirikkale, Turkey
来源：
POLYMER BULLETIN | 2013年 / 70卷 / 10期
关键词：
Conducting polymer; Soluble polymer; Thiazole polymers; Poly(2-aminothiazole); Chemical polymerization; ELECTROCHEMICAL SYNTHESIS; ELECTROCHROMIC PROPERTIES; ELECTROPOLYMERIZATION; POLYMERIZATION; POLYPYRROLE; POLYMERS; POLYTHIAZOLES; COPOLYMER; IONS;
D O I：
10.1007/s00289-013-0992-2
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(2-aminothiazole), (P-2AT), was synthesized by chemical polymerization method using 2-aminothiazole as the monomer. Structural characterizations were carried out by Fourier transform infrared, nuclear magnetic resonance, UV-vis spectroscopy, elemental analysis and scanning electron microscopy techniques. Thermal characterizations were carried out by thermogravimetric analysis and differential scanning calorimetry techniques. The number average molecular weight, M-n, of the polymer was determined by gel permeation chromatography. The effects of monomer and initiator concentration and polymerization time on the polymer yield were also studied. The solubility of the P-2AT was tested in common organic solvents as well as in acidic and basic solutions. P-2AT was soluble in DMSO, THF and DMF and its conductivity value measured 3 x 10(-6) S/cm.
引用
收藏
页码：2843 / 2856
页数：14
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