Ionothermal Synthesis of Four New Nickel Thiophosphate Anions: [Ni(P2S8)2]2-, [Ni(P3S9)(P2S8)]3-, [Ni(P3S9)2]4-, and [(NiP3S8)4(PS4)]7-

被引：23

作者：

Cody, Jason A. ^{[1
]}

Finch, Kenneth B. ^{[1
]}

Reynders, Gilbert J., III ^{[1
]}

Alexander, Grant C. B. ^{[1
]}

Lim, Hyung G. ^{[1
]}

Nather, Christian ^{[2
]}

Bensch, Wolfgang ^{[2
]}

机构：

[1] Lake Forest Coll, Dept Chem, Lake Forest, IL 60045 USA

[2] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 24期

关键词：

TEMPERATURE IONIC LIQUIDS; PHOSPHORUS; CHEMISTRY; MIXTURES; PRODUCTS; POLYMERS; SULFUR; PHASES; P4S10; GD;

D O I：

10.1021/ic302112g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new nickel thiophosphate anions have been isolated as 1-ethyl-3-methylimidazolium (EMIM) salts: [EMIM](2)[Ni(P2S8)(2)] (1), [EMIM](3)[Ni(P3S9)(P2S8)] (2), [EMIM](4)[Ni(P3S9)(2)] (3), and [EMIM](7)[(NiP3S8)(4)(PS4)] (4). Single crystals of each were prepared by ionothermal reaction of the elements in [EMIM][BF4]. 1 can also be obtained from [EMIM][CF3SO3]. In all four anions, Ni atoms are octahedrally coordinated and P atoms are tetrahedrally coordinated. In the anion found in 1, two tridentate 1,3-P2S82- ligands are cis to each other. The anion in 2 contains two different tridentate thiophosphate ligands, 1,3-P2S82- and P3S93-, whereas the anion in 3 consists of two P3S93- ligands coordinated to the central Ni atom. The anion in 4 is complex, consisting of four NiP3S8- clusters surrounding a central PS4 tetrahedron; within the NiP3S8- groups, one P atom is directly bound to Ni. The discovery of these four new compounds demonstrates the versatility of ionothermal methods for the synthesis of novel thiophosphates.

引用

页码：13357 / 13362

页数：6

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