Synthesis, crystal structure and catalytic property of a cadmium(II) coordination polymer derived from a zwitterionic carboxylate ligand

被引：4

作者：

Zhang, Jian-Wei ^{[1
]}

Cheng, Yan ^{[2
]}

Liu, Shu-Hua ^{[2
]}

机构：

[1] Qingdao Univ, Dept Environm Sci, Qingdao, Shandong, Peoples R China

[2] Shandong Acad Sci, Shandong Anal & Test Ctr, Jinan 250014, Shandong, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2018年 / 48卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Cadmium coordination polymer; crystal structure; zwitterionic carboxylate; catalytic property; METAL-ORGANIC FRAMEWORKS; METHYL-3-HYDROXY-5-CARBOXY-2-THIOPHENECARBOXYLATE; CYANOSILYLATION; CONSTRUCTION;

D O I：

10.1080/24701556.2019.1569050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cadmium(II) zwitterionic coordination polymer, {[Cd(cbdcp)(H2O)(4)]center dot H2O}(n), (1) was synthesized based on the 1-(3,5-dicarboxybenzyl)-4,4'-bipyridinium bromide (H(3)cbdcpBr) organic linker. In 1, Cd(II) cations are connected by cbdcp(2-) anions to form a one-dimensional chain structure, which are further connected to generate a hydrogen bonded-extended three-dimensional supramolecular network. Furthermore, thermal stability and catalyitic activity of 1 have also been investigated.

引用

页码：347 / 351

页数：5

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