Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property

被引：0
|
作者：
Cui Peng [1 ]
Jing Xiao-Fei [2 ]
Ren Hao [1 ]
Yuan Ye [2 ]
Zhu Guang-Shan [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 09期
关键词：
Friedel-Crafts alkylation reaction; porous aromatic framework; gas sorption; COVALENT-ORGANIC FRAMEWORK; CARBON-DIOXIDE CAPTURE; MICROPOROUS POLYMERS; TARGETED SYNTHESIS; CONSTRUCTION; CO2; DESIGN;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A porous aromatic framework, PAF-9 derived from tetraphenylgermane as basic building unit, was synthesized via Friedel-Crafts alkylation reaction. The microstructure and pore property were investigated by FTIR spectroscopy, powder X-ray diffraction, solid state NMR, thermogravimetric analysis and low temperature N-2 adsorption-desorption measurements. The characterizations reveal that PAF-9 possess high thermal and chemical stability as well as high BET surface area of 334 m(2).g(-1). Additionally, the resulting PAF materials exhibit high CO2 adsorption ability.
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页码：1855 / 1859
页数：5
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