Thermolysis of a hybrid organic-inorganic supramolecular coordination assembly: Templating the formation of nanostructured fibrous materials and carbon-based microcapsules

被引：45
|
作者：
Schmitt, W
Hill, JP
Malik, S
Volkert, CA
Ichinose, I
Anson, CE
Powell, AK
机构：
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
[2] Int Ctr Young Scientists, Natl Inst Mat Sci, Tsukuba, Ibaraki 3050044, Japan
[3] Forschungszentrum Karlsruhe, Inst Mat Forsch, D-76344 Eggenstein Leopoldshafen, Germany
[4] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany
[5] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 43期
关键词：
iron; nanostructures; organic-inorganic hybrid composites; supramolecular chemistry; thermochemistry;
D O I：
10.1002/anie.200501748
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Burning a honeycomb: An exceptional hybrid organic-inorganic coordination assembly with an extended 3D structure that contains vast separated organic and inorganic regions has been prepared (see picture of its supramolecular structure and a scanning electron micrograph image). This hybrid is used as a template in thermolysis reactions to yield nano- and microsized products whose properties are determined by those of the precursor compounds. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7048 / 7053
页数：6
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