Enantioselective Diels-Alder reactions catalyzed by chiral magnesium Lewis acids prepared from hydroxysulfoxides

被引：37
|
作者：
Ordonez, M [1 ]
GuerrerodelaRosa, V [1 ]
Labastida, V [1 ]
Llera, JM [1 ]
机构：
[1] UNIV SEVILLA,FAC FARM,DEPT QUIM ORGAN & FARMACEUT,E-41071 SEVILLE,SPAIN
来源：
TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 09期
关键词：
D O I：
10.1016/0957-4166(96)00344-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Enantioselective Diels-Alder reactions were conducted successfully using chiral magnesium complexes prepared from magnesium iodide and chiral hydroxysulfoxides derived from (R)- and (S)-methyl 1-naphthyl sulfoxide. Convenient methods for the preparation of these chiral sulfoxides have also been developed. Hydroxysulfoxide 6 (and its enantiomer 10) showed the highest enantioselectivity. Copyright (C) 1996 Elsevier Science Ltd
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收藏
页码：2675 / 2686
页数：12
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