Interesting Features of n2D Rydberg Series Fine-Structure Splittings along the Sodium-Like Isoelectronic Sequence

被引:0
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作者
Wang Xiao-Lu [1 ]
Liu Ling-Tao [1 ]
GAo Xiang [1 ]
Shen Chun [1 ]
Li Jia-Ming [1 ,2 ]
机构
[1] Shanghai Jiao Tong Univ, Shanghai Key Lab Laser Fabricat & Mat Sci, Dept Phys, Shanghai 200240, Peoples R China
[2] Tsinghua Univ, Dept Phys, Minist Educ, Key Lab Atom & Mol Nanosci, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
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中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Using a simplified multi-configuration Dirac-Fock (SMCDF) scheme based on the multi-configuration Dirac-Fock (MCDF) theory, we study the systematic variations of the fine-structure splittings of n(2)D(3/2,5/2) Rydberg series along the sodium-like isoelectronic sequence, i.e. the fine-structure orderings vary with increasing atomic number Z. The competition between the spin-orbit interactions and the exchange interactions due to relativistic effects of the nd orbital wave functions well explain such variations. Furthermore, the effect of Breit interactions which plays the secondary role is studied.
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页码:4244 / 4247
页数:4
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