Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer-metal complex, silica-supported alginic acid-amino acid-Pt complex

被引：57
|
作者：
Wei, WL [1 ]
Zhu, HY [1 ]
Zhao, CL [1 ]
Huang, MY [1 ]
Jiang, YY [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
REACTIVE & FUNCTIONAL POLYMERS | 2004年 / 59卷 / 01期
关键词：
silica-supported alginic acid-amino acid-Pt complex; asymmetric hydrogenation; furfuryl alcohol; (S)-(+)-tetrahydrofurfuryl alcohol;
D O I：
10.1016/j.reactfunctpolym.2003.10.004
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A biopolymer containing metal complex, silica-supported alginic acid-amino acid (L-alanine, L-glutamic acid, L-serine or L-lysine)-Pt complex, SiO2-AA-aa-Pt (SiO2-AA-ala-Pt, SiO2-AA-glu-Pt, SiO2-AA-ser-Pt, SiO2-AA-lys-Pt) has been prepared and found to be able to catalyze the asymmetric hydrogenation of furfuryl alcohol to give (S)(+)-tetrahydrofurfuryl alcohol at 30 degreesC and under 1 atmH(2). Among of them, SiO2-AA-glu-Pt complex catalyst is most effective for this asymmetric reaction and 84.4% product yield and 98.3% ee optical yield can be obtained, respectively. This catalyst can be reused several times without large change in the optical catalytic activity. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：33 / 39
页数：7
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