Research Progress on Enantioselective Desymmetrization Reactions Involving Metal Carbenes

被引：11
|
作者：
Teng Ming-Yu [1 ]
Han Tao [1 ]
Huang En-He [2 ]
Ye Long-Wu [1 ,2 ,3 ]
机构：
[1] Yunan Normal Univ, Coll Chem & Chem Engn, Kunming 650500, Yunnan, Peoples R China
[2] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 42卷 / 10期
基金：
中国国家自然科学基金;
关键词：
diazo compounds; metal carbene; desymmetrization; aymmetric synthesis; C-H INSERTION; CARBON-HYDROGEN INSERTION; INTRAMOLECULAR BUCHNER REACTION; BOND INSERTION; ASYMMETRIC-SYNTHESIS; CATALYZED REACTIONS; ORGANIC-SYNTHESIS; DIAZOACETATES; DIAZOKETONES; ACTIVATION;
D O I：
10.6023/cjoc202206041
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Metal carbenes have been widely applied in organic synthesis, and they can undergo a variety of chemical transformations due to their versatile reactivities. In this review, the desymmetrization of C-H insertion reaction, Buchner reaction, Si-H insertion reaction and B-H insertion reaction involving metal carbenes is introduced according to the different reaction types of metal carbenes. Under the catalysis of chiral rhodium, ruthenium and copper catalysts, chiral carbocycles, heterocycles, organosilicons and organoborons can be obtained with high enantioselectivity, which greatly enriches the development of asymmetric synthetic chemistry.
引用
收藏
页码：3295 / 3301
页数：7
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