Configurational stability of [Di(amino)silyl]lithiums having cyclic structures

被引：10

作者：

Kawachi, A ^{[1
]}

Maeda, H ^{[1
]}

Tamao, K ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 06期

关键词：

D O I：

10.1021/om010963m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclic diamino-substituted silyllithiums, [(N,N'-diisopropyldiamino)silylllithiums, were prepared by the reaction of lithium with the corresponding chlorosilanes. The methyls in the isopropyl groups are diastereotopic and anisochronous at room temperature in THF and in diglyme. Variable-temperature NMR experiments revealed that the configuration at the lithium-bearing silicon atom is stable up to 333 K in THF and 388 K in diglyme.

引用

页码：1319 / 1321

页数：3

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