High switchable dielectric phase transition originating from distortion in inorganic-organic hybrid materials (H2dabco-C2H5) [MIICl4] (M = Co, Zn)

Two phase transition materials (H(2)dabco-C2H5)[ZnCl4] and (H(2)dabco-C2H5)[CoCl4 were synthesized and characterized. Differential scanning calorimetry detected that the two compounds underwent reversible phase transitions at 245 K and 261 K, respectively. The temperature dependence of the dielectric measurements also confirmed the phase transition. Variable-temperature single-crystal X-ray diffraction suggested that the two compounds underwent the same phase transitions from the space group Pnma to P2(1)/c but at different temperatures. Symmetry breaking occurred with an Aizu notation of mmmF2/m. The structural phase transitions of 1 and 2 were ascribed to the distortion of a [H(2)clabco-C2H5](2+) cation from inorganic-organic hybrid materials (H(2)dabco-C2H5)[(MCl4)-Cl-II] (M = Zn, Co). The strong variations of dielectric anomaly made compounds 1 and 2 applicable for use in promising switchable dielectric materials.