Treatment of wood industry wastewater by combined coagulation-flocculation-decantation and fenton process

被引:18
|
作者
Azimi, Seyyedeh Cobra [1 ,2 ]
Shirini, Farhad [1 ]
Pendashteh, Alireza [2 ,3 ]
机构
[1] Univ Guilan, Fac Sci, Dept Chem, Rasht, Iran
[2] Univ Guilan, Dept Water & Environm Engn, Caspian Sea Basin Res Ctr, Rasht, Iran
[3] Univ Guilan, Dept Chem Engn, Fac Engn, Rasht, Iran
关键词
central composite design; coagulation-flocculation-decantation; fenton process; polyacrylamide; wood industry wastewater; PAPER-MILL EFFLUENT; HYDROGEN-PEROXIDE OXIDATION; POLLUTANT REMOVAL; PROCESS DESIGN; COD REMOVAL; PULP; DEGRADATION; ADSORPTION; COLOR; DECOLORIZATION;
D O I
10.1002/wer.1441
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the present research, the efficiency of turbidity and chemical oxygen demand (COD) reduction from the wood industry wastewater (WIW) by the use of a combined coagulation-flocculation-decantation (CFD) - Fenton process was studied. Firstly, the performance of three coagulants such as ferric chloride (FeCl3), aluminum sulphate (alum), and polyaluminum chloride (PACl) was evaluated. The polyacrylamide (PAM) was used as a flocculant. The results showed that the polyaluminum chloride had a high removal efficiency. The COD reduction of 84.1% and turbidity removal of 82.0% of were obtained in coagulation-flocculation-decantation (CFD). Secondly, Fenton process was optimized, by the use of a response surface methodology (RSM), with application of a central composite design (CCD). The maximum turbidity and COD removal obtained by this process were 94.1% and 72.5% respectively, under optimal conditions ([Fe2+] = 250 mg/L, [H2O2] = 500 mg/L, pH 3.5, time 60 min). The kinetics of COD and turbidity removal were determined by the model of first order. In conclusion, the combination of coagulation-flocculation-decantation (CFD) - Fenton process presented as a remarkable method for wood wastewater treatment. Practitioner points A combination of coagulation-flocculation-decantation and Fenton process was introduced for the wood industry wastewater treatment. A designed experimental approach for treatment of wood industry wastewater using a Fenton process was studied. The yields of COD, BOD5, N-NO3, P-PO4, and dye removal were obtained according to the standard limits in Iran.
引用
收藏
页码:433 / 444
页数:12
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