Dinuclear and tetranuclear oxo-bridged iron(III) complexes of the ambidentate ligand 3-(2-pyridyl)-pyrazole

被引：47
|
作者：
Jones, PL
Jeffery, JC
McCleverty, JA
Ward, MD
机构：
[1] School of Chemistry, University of Bristol, Cantock's Close
来源：
POLYHEDRON | 1997年 / 16卷 / 09期
基金：
英国工程与自然科学研究理事会;
关键词：
iron-oxo complexes; pyrazolate bridge; polynuclear complexes; crystal structures;
D O I：
10.1016/S0277-5387(96)00457-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structures of [Fe-4(III)(HL)(2)(L)(6)(mu-O)(2)[PF6](2) . 4MeCN (1 . 4MeCN) and [Fe-2(III)(HL)(4) (OSO3)(2)(mu-O)]. 2MeOH . 3H(2)O (2 . MeOH . 3H(2)O) have been determined [HL is the ambidentate, potentially terdentate ligand 3-(2-pyridyl)-pyrazole] : complex 2 is a conventional mu-oxo-diiron(III) complex in which HL acts as a bidentate chelate and the sulfate ligands are monodentate, but 1 is effectively a dimer containing two mu-oxo-diiron(III) cores linked by deprotonated ligands L(-) which are bridging via the two N atoms of the pyrazolate rings. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：1567 / 1571
页数：5
相关论文
共 50 条
  • [1] Syntheses, structures and magnetic properties of dinuclear oxo-bridged iron(III) complexes
    Shin, Jong Won
    Rowthu, Sankara Rao
    Lee, Ju Eun
    Lee, Hong In
    Min, Kil Sik
    POLYHEDRON, 2012, 33 (01) : 25 - 32
  • [2] SYNTHESIS AND MAGNETIC-PROPERTIES OF OXO-BRIDGED TETRANUCLEAR IRON(III) AND MANGANESE(III) COMPLEXES
    NISHIDA, Y
    NASU, M
    TOKII, T
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (04): : 567 - 570
  • [3] BINUCLEAR OXO-BRIDGED IRON(III) COMPLEXES
    MURRAY, KS
    COORDINATION CHEMISTRY REVIEWS, 1974, 12 (01) : 1 - 35
  • [4] Nucleophilic and electrophilic promotion of ligand substitution reactions in oxo-bridged, dinuclear chromium(III) complexes
    Bessire, DR
    Holwerda, RA
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1999, 31 (05) : 351 - 356
  • [5] Molybdenum- and tungsten(II) monometallic 3-(2-pyridyl)pyrazole and bimetallic 3-(2-pyridyl)pyrazolate complexes
    Arroyo, Marta
    Miguel, Daniel
    Villafane, Fernando
    Alegria, Elisabete C. B.
    Pombeiro, Armando J. L.
    DALTON TRANSACTIONS, 2012, 41 (23) : 7017 - 7025
  • [6] Unsupported hydroxo- and oxo-bridged binuclear iron(III) complexes of pyridyl bis(aminophenol) ligands
    Shakya, Rajendra
    Houser, Robert P.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [7] A NOVEL OXO-BRIDGED DINUCLEAR HEPTA-COORDINATED IRON(III) COMPLEX
    Bacchi, A.
    Pelizzi, G.
    Ivanovic-Burmazovic, I.
    Andjelkovic, K.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 422 - 422
  • [8] Synthesis and structure of a copper(II) tetranuclear complex of 3-(6-methyl-2-pyridyl)-5-(2-pyridyl)pyrazole ligand
    Pons, J
    Sanchez, FJ
    Casabó, J
    Alvarez-Larena, A
    Piniella, JF
    Ros, J
    INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (07) : 833 - 836
  • [9] Linear and bent oxo-bridged dinuclear rhenium(V) complexes with terminal and bridging pyrazole ligands
    Machura, B
    Dziegielewski, JO
    Kruszynski, R
    Bartczak, TJ
    Kusz, J
    INORGANICA CHIMICA ACTA, 2004, 357 (04) : 1011 - 1022
  • [10] Binuclear oxo-bridged iron(III) complexes of chiral tetradentate ligands
    Glerup, J
    Michelsen, K
    Arulsamy, N
    Hodgson, DJ
    INORGANICA CHIMICA ACTA, 1998, 274 (02) : 155 - 166
12345