Four Rhodamine B-based fluorescent chemosensor for Fe3+ in aqueous solution

被引：56
|
作者：
Chai, Meimei [1 ]
Zhang, Di [1 ]
Wang, Min [1 ]
Hong, Huijie [1 ]
Ye, Yong [1 ,2 ]
Zhao, Yufen [1 ,2 ,3 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Phosphorus Chem Engn Res Ctr Henan Prov, Zhengzhou 450052, Peoples R China
[2] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China
[3] Xiamen Univ, Coll Chem & Chem Engn, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Peoples R China
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2012年 / 174卷
基金：
美国国家科学基金会;
关键词：
Rhodamine B; Fe3+; Fluorescent probes; On-off; SENSOR; CU2+; IRON; SPIROLACTAM; DESIGN;
D O I：
10.1016/j.snb.2012.08.003
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A series of Rhodamine B derivative was synthesized and characterized by NMR, HR-MS and IR. The probes exhibited highly selective and sensitive recognition toward Fe3+ over other metal ions. The significant changes in the fluorescence color could be used for naked-eye detection. The Job's plot, MS, IR and H-1 NMR indicated the formation of 1:2 complexes between 1 and Fe3+. The reversibility establishes the potential of these probes as chemosensors for Fe3+ detection. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：231 / 236
页数：6
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