Electrochemical synthesis of Ba2Ag8S7, a quasi-one-dimensional barium silver(I) sulfide containing mixed S2-/S22- ligands

被引：0

作者：

Li, H ^{[1
]}

Hwu, SJ ^{[1
]}

机构：

[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 20期

关键词：

barium; electrochemistry; polychalcogenides; silver; solid-state structures; sulfur;

D O I：

10.1002/(SICI)1521-3773(19991018)38:20<3067::AID-ANIE3067>3.0.CO;2-B

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stingray pattern is adopted by Ba2Ag8S7. Crystals of this compound were grown in a two-electrode chemical cell from a BaS3/ethylenediamine solution. In the pseudo-one-dimensional structure columns of ∞/1[Ag8S7] (shown in the picture) are stacked head-to-tail to create voids where the barium atoms reside. The coexistence of S2- and S22- indicates a reductive decomposition [Eq. (1)].

引用

页码：3067 / 3070

页数：4

共 47 条

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